Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles

Thumbnail Image
molecules-28-04015.pdf (6.12 MB)
Authors
Barbasiewicz, Michał
Fedoryński, Michał
Loska, Rafał
Mąkosza, Mieczysław
Date
2023
Journal Title
Journal ISSN
Volume Title
Publisher
MDPI
License
Creative Commons License
Creative Commons Attribution 4.0 International License
Abstract
The aim of this essay is to disclose the similarity of a great variety of reactions that proceed between nucleophiles and pi-electrophiles—both aromatic and aliphatic. These reactions proceed via initial reversible addition, followed by a variety of transformations that are common for the adducts of both aliphatic and aromatic electrophiles. We hope that understanding of this analogy should help to expand the scope of the known reactions and inspire the search for new reactions that were overlooked.
Description
Keywords
nucleophilic substitution    nucleophilic addition    nucleophiles    electrophiles    elimination    nitroarenes    reaction mechanisms
Citation
Molecules 2023, 28(10), 4015 ; https://doi.org/10.3390/molecules28104015
URI
https://depot.ceon.pl/handle/123456789/23234
Belongs to collection
Artykuły IChO PAN